期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 11, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201702716
关键词
crystal structures; ionic conductivities; solid electrolytes; solid-state batteries; sulfides
类别
资金
- Basic Science Research Program [NRF-2017M1A2A2044501]
- Leading Foreign Research Institute Recruitment Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT AMP
- Future Planning [NRF-2017K1A4A3015437]
- Materials and Components Technology Development Program of MOTIE/KEIT [10076731]
Sulfide Na-ion solid electrolytes (SEs) are key to enable room-temperature operable all-solid-state Na-ion batteries that are attractive for large-scale energy storage applications. To date, few sulfide Na-ion SEs have been developed and most of the SEs developed contain P and suffer from poor chemical stability. Herein, discovery of a new structural class of tetragonal Na4-xSn1-xSbxS4 (0.02 x 0.33) with space group I4(1)/acd is described. The evolution of a new phase, distinctly different from Na4SnS4 or Na3SbS4, allows fast ionic conduction in 3D pathways (0.2-0.5 mS cm(-1) at 30 degrees C). Moreover, their excellent air stability and reversible dissolution in water and precipitation are highlighted. Specifically, TiS2/Na-Sn all-solid-state Na-ion batteries using Na3.75Sn0.75Sb0.25S4 demonstrates high capacity (201 mA h (g of TiS2)(-1)) with excellent reversibility.
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