期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 20, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201800715
关键词
-COOH group; organic dyes; passivation; perovskite solar cells
类别
资金
- New Energy and Industrial Technology Development Organization (NEDO, Japan)
- Science Fund for Creative Research Groups [21421004]
- NSFC/China [21772040, 21372082, 2157062, 11574199, 11674219]
- Fundamental Research Funds for the Central Universities [222201717003]
- Programme of Introducing Talents of Discipline to Universities [B16017]
- China Scholarship Council (CSC)
Organic-inorganic halide perovskites are efficient absorbers for solar cells. Nevertheless, the trap states at the surfaces and grain boundaries are a detrimental factor compromising the device performance. Here, an organic dye (AQ310) is employed as passivator to reduce the trap states of the perovskites and promote better stability. The results demonstrate that the trap states of perovskite are minimized by the presence of AQ310's COOH group and the formation of coordination with under-coordinated Pb2+ ions. The resulting carrier recombination time is prolonged and verified by the photoluminescence and open-circuit voltage decay measurements. Consequently, the best average power conversion efficiency (PCE) of 19.43% is achieved for the perovskite solar cell (PSC) with AQ310 passivation, as compared with a low average PCE of 17.98% for the PSC without AQ310 passivation.
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