期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 19, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201703612
关键词
core-shell with concentration gradient; layered NCA cathodes; lithium-ion batteries; nickel-rich cathodes
类别
资金
- Global Frontier R&D Program of the Center for Hybrid Interface Materials (HIM) - Ministry of Science, Information & Communication Technology (ICT) [2013M3A6B1078875]
- National Research Foundation of Korea (NRF) - Korea government Ministry of Education and Science Technology (MEST) [NRF-2018R1A2B3008794]
A Ni-rich concentration-gradient Li[Ni0.865Co0.120Al0.015]O-2 (NCA) cathode is prepared with a Ni-rich core to maximize the discharge capacity and a Co-rich particle surface to provide structural and chemical stability. Compared to the conventional NCA cathode with a uniform composition, the gradient NCA cathode exhibits improved capacity retention and better thermal stability. Even more remarkably, the gradient NCA cathode maintains 90% of its initial capacity after 100 cycles when cycled at 60 degrees C, whereas the conventional cathode exhibits poor capacity retention and suffers severe structural deterioration. The superior cycling stability of the gradient NCA cathode largely stemmed from the gradient structure combines with the Co-rich surface, which provides chemical stability against electrolyte attack and reduces the inherent internal strain observed in all Ni-rich layered cathodes in their charged state, thus providing structural stability against the repeated anisotropic volume changes during cycling. The high discharge capacity of the proposed gradient NCA cathode extends the driving range of electric vehicles and reduces battery costs. Furthermore, its excellent capacity retention guarantees a long battery life. Therefore, gradient NCA cathodes represent one of the best classes of cathode materials for electric vehicle applications that should satisfy the demands of future electric vehicles.
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