期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 11, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201702734
关键词
bifunctional oxygen electrocatalysts; Co3O4; metal-organic frameworks; OER; ORR
类别
资金
- University of Science and Technology of China
- National Natural Science Foundation of China [21607147, 21590812, 51538011]
- Collaborative Innovation Centre of Suzhou Nano Science and Technology of the Ministry of Education of China
The development of high-efficiency bifunctional electrocatalyst for oxygen reduction and evolution reactions (ORR/OER) is critical for rechargeable metal-air batteries, a typical electrochemical energy storage and conversion technology. This work reports a general approach for the synthesis of Pd@PdO-Co3O4 nanocubes using the zeolite-type metal-organic framework (MOF) as a template. The as-synthesized materials exhibit a high electrocatalytic activity toward OER and ORR, which is comparable to those of commercial RuO2 and Pt/C electrocatalysts, while its cycle performance and stability are much higher than those of commercial RuO2 and Pt/C electrocatalysts. Various physicochemical characterizations and density functional theory calculations indicate that the favorable electrochemical performance of the Pd@PdO-Co3O4 nanocubes is mainly attributed to the synergistic effect between PdO and the robust hollow structure composed of interconnected crystalline Co3O4 nanocubes. This work establishes an efficient approach for the controlled design and synthesis of MOF-templated hybrid nanomaterials, and provides a great potential for developing high-performance electrocatalysts in energy storage and conversion.
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