期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 21, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201800625
关键词
100% H-2 conversion; 100% H-2 selectivity; hydrazine borane; hydrogen generation; noble-metal-free catalysts
类别
资金
- National Natural Science Foundation of China [51522101, 51471075, 51631004, 51401084]
- Program for JLU Science and Technology Innovative Research Team [2017TD-09]
- Fundamental Research Funds for the Central Universities
Efficient and selective dehydrogenation of hydrazine borane (HB), a novel hydrogen storage material with very high hydrogen content (HB, 15.4 wt%), is a key challenge for a fuel-cell-based hydrogen economy. However, even using the noble metal catalysts for HB decomposition, the activities are still far from satisfying, to say nothing of non-noble-metal-containing catalysts. In response, as a proof-of-concept experiment, herein, noble-metal-free NiFe-CeOx nanoparticles are successfully immobilized on an MIL-101 support without surfactant by a simple liquid impregnation method. Unexpectedly, the resultant Ni0.5Fe0.5-CeOx/MIL-101 catalyst shows good performance, including 100% H-2 selectivity, 100% conversion, and record catalytic activity (351.3 h(-1)) for hydrogen generation at mild temperature, which is even better than most of the noble metal heterogeneous catalysts and might be attributed to the good dispersion and uniform particle size of the Ni0.5Fe0.5-CeOx nanoparticles due to steric restrictions effect of the MIL-101 support. Additionally, extending MIL-101 to some other important kinds of metal-organic framework (MOF) structures, the resultant NiFe-CeOx/MOF catalysts all show good catalytic activity toward HB decomposition, showing the universality of the MOF supported NiFe-CeOx catalysts.
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