期刊
ACS CATALYSIS
卷 8, 期 8, 页码 7351-7355出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b02052
关键词
alpha-boryl ketones; alkynes; borane adducts; gold catalyst; organoboron
资金
- National Natural Science Foundation of China [21625204, 21790332, 21532003]
- 111 project of the Ministry of Education of China [B06005]
- National Program for Special Support of Eminent Professionals
- Fundamental Research Funds for the Central Universities
Herein, we report a gold-catalyzed oxidative coupling reaction of terminal alkynes and borane adducts for the synthesis of alpha-boryl carbonyl compounds, which are versatile organoboron reagents and could undergo various synthetic transformations. This efficient, regiospecific reaction showed good functional group tolerance and could be used for late-stage modification of structurally complex bioactive compounds.
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