期刊
ACS CATALYSIS
卷 8, 期 7, 页码 6699-6706出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b01675
关键词
catalysis; C8-alkylation; C-H bond activation; 1-naphthylamine; picolinamide; rhodium catalyst
资金
- MEXT [17H06091]
The rhodium(I)-catalyzed C-H alkylation of 1-naphthylamide derivatives with alkenes at the C8-position using a picolinamide directing group is reported. Various alkenes including styrene derivatives, alpha,beta-unsaturated carbonyl compounds, and even unactivated alkene could also be used as coupling partners. The reaction mechanism was investigated in kinetic studies, deuterium labeling studies, and control experiments. The reaction appears to proceed through a rhodium carbene intermediate, which is generated from an alkene.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据