期刊
ACS CATALYSIS
卷 8, 期 7, 页码 6094-6099出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b01823
关键词
palladium catalysis; Suzuki-Miyaura reaction; migrative cross-coupling; allylic compounds; regioselectivity
资金
- Natural Science Foundation of China [21502080, 21772071, 21290180, 21772076, 21372104, 21472077]
- fundamental research funds for the central universities [lzujbky-2017-116]
- 111 Program of MOE
The hydroboration/Pd-catalyzed migrative Suzuki-Miyaura cross-coupling of 1,3-dienes with electron deficient aryl halides has been developed, which enables the synthesis of branched allylarenes directly from primary homoallylic alkyl boranes. A ligand-tuned linear- or branch-selective coupling for these aryl halides has also been achieved.
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