期刊
ACS CATALYSIS
卷 8, 期 7, 页码 6401-6406出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b00707
关键词
photocatalysis; redox neutral; remote functionalization; alkene; radical; oxy-alkylation; carbo-alkylation
资金
- European Research Council (ERC Starting grant) [307948]
- Swiss National Science Foundation [SNF 200020_146853]
- COST Action CHAOS [CA15106]
A photoinduced cascade strategy is presented here for the remote functionalization of alkenes under redox neutral conditions. A broad portfolio of alkyl groups has been added to double bonds to produce, upon 1,5-HAT, remote C-centered radicals which can be harvested in the presence of O- or C-nucleophiles to efficiently form Csp(3)-O and Csp(3)-Csp(2) bonds at room temperature.
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