期刊
ACS CATALYSIS
卷 8, 期 6, 页码 5085-5144出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b00743
关键词
potassium persulfate; C-H functionalizations; oxidative transformations; sulfate radical anion; radical reactions
资金
- SERB, New Delhi [ECR/2016/001474]
- Centre of Biomedical Research, Lucknow
Carbon carbon/carbon heteroatom bond formation via oxidative transformations is a heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has emerged as a cost-effective, suitable inorganic oxidant for a wide array of oxidative transformations, ranging from laboratory experiments to industrial processes. The current review provides a comprehensive coverage of oxidative transformations aided with K2S2O8 in the presence or absence of a transition-metal catalyst, critical assessment of the results, and underlying mechanisms. Organic chemists may find this review to be a useful guide for the expedient synthesis of new chemical entities, to formulate mechanistic manifolds involving the sulfate radical anion, or to design novel oxidative transformations. A detailed understanding of the unsolved mechanisms could further enrich the field.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据