期刊
ACS CATALYSIS
卷 8, 期 3, 页码 2595-2600出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b03817
关键词
OER; sacrificial Al; nickel phosphide; in situ catalyst formation; PGM-free catalyst
资金
- European Union's Horizon 2020 research and innovation program through the CritCat Project [686053]
- FROnTHERA project - European Union Funds, through Portuguese NORTE 2020 programme [NORTE-01-0145-FEDER-000023]
- FCT [SFRH/BD/7939/2011]
- Iowa State University
We report a simple low-cost concept for the preparation of water-oxidation electrocatalyst via modification of self-supported Ni5P4-Ni2P foam catalyst precursor with Al. As an anode for alkaline oxygen evolution reaction, this material exhibits an impressive Tafel slope of 27 mV dec(-1) and offers anodic current densities of 10, 100, and 300 mA cm(-2) at overpotentials of merely 180, 247, and 312 mV, respectively. Moreover, the anode demonstrates high operational stability, as reflected by a steady-state performance for more than 8 days. Combining state-of-the-art electron microscopy and photoelectron spectroscopy, we investigated the role of the Al dopant in the formation of active Ni(OH)(2)/NiO/Ni5P4-Ni2P nanocatalyst, which exhibits oxygen-evolving activity among the highest reported to date.
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