期刊
ACS CATALYSIS
卷 8, 期 4, 页码 2897-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b00221
关键词
hydrosilylation; silicon; boron; catalysis; asymmetric
资金
- NIH [GM-59417]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM059417] Funding Source: NIH RePORTER
A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral nonracemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.
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