期刊
CHEMICAL SCIENCE
卷 9, 期 8, 页码 2357-2364出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc04528j
关键词
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资金
- Fundamental Research Funds for the Central Universities [2412016KJ041]
- National Key Basic Research Program of China [2013CB834802]
- NSFC/RGC Joint Research Scheme [N_ HKU 752/08]
- University Grants Committee Areas of Excellence Scheme [AoE/P-03/08]
- National Science Foundation of China [21471027, 21601032]
Pincer platinum(II) complexes are well documented to exhibit weak intermolecular interactions in the solid state and 77 K glassy solutions, leading to emissive triplet metal-metal-to-ligand charge transfer ((MMLCT)-M-3) excited states that often vanish in dilute solutions. In this work, metal-organic framework (MOF) materials are introduced to provide a solid solution environment for easy access to 3MMLCT excited states of pincer platinum(II) complexes. Phosphorescent composites Pt-II@MOFs (1-4) with matrix-dependent monomers and oligomer emission properties were obtained. These Pt-II@MOFs are efficient catalysts for photoinduced dehydrogenation reactions.
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