期刊
CHEMICAL SCIENCE
卷 9, 期 18, 页码 4325-4332出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc01113c
关键词
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资金
- European Research Council (ERC) [646747]
- NWO-CW [016122613]
- University of Amsterdam (RPA Sustainable Chemistry)
- DFG [INST41/864]
The iridium(iii/iv/v) imido redox series [Ir(NtBu){N(CHCHPtBu2)(2)}](0/+/2+) was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium(iv) imide exhibits an electronic doublet ground state with considerable imidyl' character as a result of covalent Ir-NtBu bonding. Reduction gives the neutral imide [Ir(NtBu){N(CHCHPtBu2)(2)}] as the first example of an iridium complex with a triplet ground state. Its reactivity with respect to nitrene transfer to selected electrophiles (CO2) and nucleophiles (PMe3), respectively, is reported.
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