期刊
BIOSENSORS-BASEL
卷 2, 期 3, 页码 305-317出版社
MDPI AG
DOI: 10.3390/bios2030305
关键词
conducting polymer; thiol-ene; ProDOT; functionalization
资金
- University of Delaware
- US Army MURI program
- National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1103027] Funding Source: National Science Foundation
We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene ( ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.
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