期刊
WATER RESEARCH
卷 141, 期 -, 页码 32-45出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2018.04.048
关键词
Kinetic variability; Chlorine and THM model; Flow velocity effect; NOM reactivity; Wall demand
资金
- CBI group [EP-C-04-034]
- U.S. EPA through its Office of Research and Development
- National Key Research and Development Program of China [2016YFC0400600]
- National Natural Science Foundation of China [51478417]
- Science and Technology Program of Zhejiang Province [201703174]
Simultaneous chlorine decay and disinfection byproduct (DBP) formation have been discussed extensively because of their regulatory and operational significance. This study further examines chemical reaction variability in the water quality changes under various hydrodynamic conditions in drinking water distribution. The variations of kinetic constant for overall chlorine decay (k(E)) and trihalomethane (THM) formation were determined under stagnant to turbulent flows using three devices of different wall demand and two types of natural organic matters (NOM) in water. The results from the comparative experiments and modeling analyses show the relative importance of wall demand (k(w)), DBP-forming chlorine decay (k(D)), and other bulk demand (k(b)') for pipe flows of Re 0-52500. It is found that chlorine reactivity of virgin NOM is the overriding factor. Secondly, for tap water NOM of lower reactivity, pipe flow properties (Re or u) can significantly affect kE, the THM yield (7), formation potential (Y), and the time to reach the maximum THM concentration (t(max)) through their influence on kinetic ratio k(D)/(k(b)' + k(w)). These observations, corroborating with turbidity variations during experiments, cannot be explained alone by chlorine dispersion to and from the pipe wall. Mass exchanges through deposition and scale detachment, most likely being flow-dependent, may have contributed to the overall chlorine decay and DBP formation rates. Thus for the simultaneous occurrence of chlorine decay and DBP formation, model considerations of NOM reactivity, pipe types (wall demand), flow hydraulics, and their interactions are essential. (C) 2018 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据