期刊
WASTE MANAGEMENT
卷 78, 期 -, 页码 208-216出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2018.05.029
关键词
Lithium-ion batteries; Lithium iron phosphate; Recycling; Lithium phosphate; Hydrothermal process
A novel process recycling Li from the spent LiFePO4 cathode material has been put forward. The new LiFePO4 sample is synthesized through hydrothermal reaction by using recovered Li3PO4 as Li source and FeSO4 center dot 7H(2)O as Fe source. The morphologies, structure and physicochemical properties of the resynthesized LiFePO4 cathode material were characterized by Field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), Transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and electrochemical measurement. The results showed that the morphology and particle size of re-synthesized LiFePO4 samples become more regular and smaller with the increase of the hydrothermal reaction temperature. Besides, it has been found that the LiFePO4 cathode material synthesized at 200 degrees C showed excellent electrochemical properties which deliver a high initial capacity of 144.25 mAh/g at the rate of 1 C and high capacity retention of 96.7% after 200 cycles. Therefore, this work provides a new strategy for recovery and recycle of the spent LiFePO4 cathode scraps. (C) 2018 Elsevier Ltd. All rights reserved.
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