期刊
TOPICS IN CATALYSIS
卷 61, 期 9-11, 页码 784-791出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-018-0946-x
关键词
Niobium; Niobium oxide; Surface reconstruction; X-ray photoelectron diffraction
资金
- Brazilian research agency Fundacao de Amparo a Pesquisa do Estado de Sao Paulo - FAPESP [23187]
- Brazilian research agency Conselho Nacional de Desenvolvimento Cientifico e Tecnologico - CNPq [23187]
- Brazilian research agency Fapeg-Pronem [23187]
An ordered thin film of niobium oxide (NbO) was formed on the Nb(100) surface by heating the niobium single crystal at 1023 K for 2 min under an oxygen atmosphere. The surface composition was analyzed by X-ray photoelectron spectroscopy (XPS), and the surface structure was characterized by low energy electron diffraction (LEED) and X-ray photoelectron diffraction (XPD) generated by synchrotron radiation. Annealing at 1223 K in ultra-high vacuum yielded a reconstructed (3 x 1) LEED pattern. XPS measurements indicated that the surface comprised of metallic and oxidized niobium species. The comparison between experimental and theoretical XPD results indicated that 60% of the Nb(100) surface was covered by two-layered nanoislands of NbO, and 40% had bare patches.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据