期刊
THIN SOLID FILMS
卷 655, 期 -, 页码 48-53出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2018.02.010
关键词
Atomic layer deposition (ALD); High-k material; Dynamic random access memory (DRAM); Metal-insulator-metal capacitor; ZrO2; (Ta/Nb)O-x; Al2O3
类别
资金
- World Premier International Research Center Initiative (WPI)
- Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- CREST Phase Interface Science for Highly Efficient Energy Utilization [JPMJCR13C3]
- Japan Science and Technology Agency (JST)
The influence of amorphous high-k interlayers, such as Al2O3, (Ta/Nb)O-x (TN), and (Ta/Nb)O-x-Al2O3 (TNA), on the leakage current (J) and dielectric constant (k) for metal-insulator-metal capacitors with ZrO2/high-k/ZrO2 nanolaminate insulating films and TiN electrodes was investigated. The insulating films were prepared by atomic layer deposition followed by post-deposition annealing at 600 degrees C. The capacitance equivalent thickness (CET) of the capacitors increased in the order ZrO2/(Ta/Nb)O-x/ZrO2 (ZTNZ) < ZrO2/(Ta/Nb)O-x-Al2O3/ZrO2 (ZTNAZ) < ZrO2/Al2O3/ZrO2 (ZAZ), owing to the k values for Al2O3 (similar to 6), TNA (similar to 9), and TN (similar to 11). The J values at 0.6 V for capacitors with a CET of 1.1 nm increased in the order ZTNAZ < ZAZ << ZTNZ. The effect of a high-k interlayer on the J characteristics appeared above a thickness of 0.4 nm in the case of Al2O3 and TNA, while a 0.8-nm-thick TN maintained high J values. Based on these results, there are three important factors as a high-k interlayer to reduce J value, such as a band gap larger than that for TN (4.4 eV), a thickness of >= 0.4 nm, and an amorphous structure. Therefore, to achieve the low J and CET, TNA is a promising candidate material for a high-k interlayer for future dynamic random access memory.
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