期刊
TETRAHEDRON LETTERS
卷 59, 期 31, 页码 2951-2959出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.06.055
关键词
Aryl sulfoxide; C-H functionalization; Interrupted Pummerer reaction; [3,3] Sigmatropic rearrangement; Electrophilic activation
资金
- JSPS KAKENHI [JP16H04109, JP18H04252, JP18H04409, JP18K14212]
- JSPS Predoctoral Fellowship
Sulfoxide-promoted ortho-C-H functionalization reactions of aromatic compounds have emerged as powerful tools for organic synthesis. Among them, [3,3] sigmatropic rearrangement induced by interrupted Pummerer reaction or electrophilic activation of sulfoxides has proved to be a fruitful strategy due to its versatility and high reaction efficiency. This digest paper mainly focuses on recent progress on C-H functionalization reactions of aryl sulfoxides via [3,3] sigmatropic rearrangement of sulfoniumtethered intermediates. (C) 2018 Elsevier Ltd. All rights reserved.
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