期刊
TETRAHEDRON LETTERS
卷 59, 期 26, 页码 2541-2545出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.05.040
关键词
Click reaction; 1-D Cu coordination complex; 1,3-Dithioether; 1,2,3-Triazole
资金
- Science and Engineering Research Board of India [EMR/2015/000549]
A novel 1,3-bis(4-fluorophenylthio)-propane ligand based Cul 1-D polymeric coordination complex having formula ([(Cul)(2){ArS(CH2)(3)SAr}(2)](n), Ar = 4-F-C6H4) has been synthesized and characterized by H-1 NMR, C-13 NMR and single crystal XRD techniques. This complex has been employed for the first time as suitable catalyst for base-free one-pot three-component regioselective azide-alkyne cycloaddition (MC) reaction. A novel 1,2,3-triazole compound with sulfur functionalized pendant arms has also been prepared using our catalytic system in a multicomponent manner via one-pot two-step reaction. (C) 2018 Elsevier Ltd. All rights reserved.
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