期刊
TETRAHEDRON LETTERS
卷 59, 期 22, 页码 2103-2111出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.04.060
关键词
Photoredox catalysis; Alkoxy radical; Hydrogen atom transfer; beta-Scission; C-H functionalization
资金
- National Natural Science Foundation of China [21772121]
- Thousand Plan Youth program
- China Postdoctoral Science Foundation [2017M611642, 2017M611636]
Alkoxy radicals have been intensively studied as versatile synthetic intermediates with well-established reactivity and selectivity. Due to the difficulties associated with the generation of these transient and high-energy radicals, the utilization of the unique reactivity of alkoxy radicals in catalytic platforms has become a rather challenging task. Recent studies on the alkoxy radical-mediated transformations have benefited tremendously from advances in modern photoredox catalysis. In this digest, we aim to highlight reported transformations that utilize alkoxy radicals in a photocatalytic fashion, in particular, underline novel catalytic platforms which we anticipate will find broad application in the near future. (C) 2018 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据