期刊
TETRAHEDRON LETTERS
卷 59, 期 14, 页码 1317-1327出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.02.054
关键词
Transition metal; 1,2-Acyloxy migration; Propargylic carboxylate; Carbenoid; Cycloaddition
资金
- National Science Foundation of China [20802034, 21572098]
- Natural Science Foundation of Jiangsu Province [BK 2009229, BK 20141313]
Propargylic carboxylates, as a type of easily available alkyne compounds, have attracted considerable attentions in recent decade. Under the catalysis of transition metal complex (Pd, Ru, Pt, Au, Rh etc), one of chemical transformations of propargylic carboxylate is 1,2-acyloxy migration. The resultant alkenyl metallocarbenoid or metal-containing species may undergo a variety of chemical transformations, leading to formation of carbocyclic and heterocyclic compounds. In this review, representative domino reactions initiated by 1,2-acyloxy migration of propargylic carboxylates are summarized, including pentannuations, cycloadditions and rearrangements. Some mechanistic discussions and synthetic applications are also included. (C) 2018 Elsevier Ltd, All rights reserved.
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