期刊
TALANTA
卷 180, 期 -, 页码 81-89出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2017.12.026
关键词
Poly(3,4-ethylenedioxythiophene); MnO2 nanoparticles; Nanocomposites; Sulfamethazine; Square wave voltammetry
资金
- Ministry of Science and Technology of the Republic of China [MOST 106-2113-M-260-005]
The toxicity of sulfa drugs has attracted great attention, and the reported electrochemical methods for sulfa drugs usually employ a high oxidation potential. In this work, a one-pot synthesized conducting polymer nanocomposite containing poly(3,4-ethylenedioxythiophene) (PEDOT) and MnO2 was cast on a screen-printed carbon electrode (SPCE), and the modified electrode showed superior electrochemical activity over a bare electrode for sulfamethazine (SMZ) determination. The SMZ detection was based on the electrochemical oxidation product, which showed an adsorptive property and exhibited a redox couple at 0.39 V in pH 3 phosphate buffer solutions (PBS). The electrode surfaces were well characterized by the water contact angle technique, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM) and cyclic voltammetry. By the use of square wave voltammetry (SWV), a wide linear response to SMZ, from 1.0 mu M to 500 mu M, was obtained. The sensitivity and detection limits (S/N = 3) were 0.115 mu A mu M-1 and 0.16 mu M, respectively. The proposed method and a reference high-performance liquid chromatographic method (HPLC) were applied for the determination of SMZ in two real samples using the standard addition method, and satisfactory recoveries and good agreement were obtained.
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