期刊
SYNTHETIC COMMUNICATIONS
卷 48, 期 13, 页码 1657-1662出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2018.1458241
关键词
Aspicilin; S-propylene oxide; sharpless asymmetric dihydroxylation and Yamaguchi macrolactonization; witttig olefination
The total synthesis of an 18-membered polyhydroxylated macrolide (+)-Aspicilin was accomplished starting from commercially available enantiopure propylene oxide and D-(+)-gluconolactone by asymmetric synthetic approach. The key reactions involved are Witttig reaction, Sharpless asymmetric dihydroxylation, and Yamaguchi macrolactonization. [GRAPHICS] .
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