期刊
SYNTHESIS-STUTTGART
卷 50, 期 15, 页码 2908-2914出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1592000
关键词
irradiation; palladium catalysis; alkylation; heteroarenes; alkyl bromides
资金
- NSFC [21325208, 21572212]
- MOST [2017YFA0303500]
- FRFCU
- PCSIRT
- KY [2060000019]
A palladium catalyst in combination with two types of phosphine ligands efficiently catalyzes direct C-H alkylation of heteroarenes with secondary and tertiary alkyl bromides under irradiation conditions. Irradiation of blue light-emitting diodes (blue LEDs) effectively excites phosphine-ligated palladium catalyst to facilitate oxidative addition with alkyl bromides, and also excites the alkylpalladium species to enable the generation of alkyl radicals to react with heteroarenes.
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