期刊
SYNLETT
卷 29, 期 9, 页码 1211-1214出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/S-0036-1591774
关键词
iron catalysis; Grignard reagents; cross-coupling; allylic substitution; allylic ethers
资金
- JSPS KAKENHI [25810064]
- Grants-in-Aid for Scientific Research [25810064] Funding Source: KAKEN
We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac)(3) to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.
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