期刊
SURFACE SCIENCE REPORTS
卷 73, 期 3, 页码 83-115出版社
ELSEVIER
DOI: 10.1016/j.surfrep.2018.03.001
关键词
Halogens; Adsorption; Structural phase transitions; Metal surfaces; Atomic structure; Lateral interactions; Surface halide; Surface reconstruction; Surface chemical reactions; Scanning tunneling microscopy; Density functional theory
资金
- Russian Foundation for Basic Research [15-02-99607-a, 15-02-99542-a]
This paper presents a review of the experimental and theoretical investigations of halogen interaction with metal surfaces. The emphasis was placed on the recent measurements performed with a scanning tunneling microscope in combination with density functional theory calculations. The surface structures formed on metal surface after halogen interaction are classified into three groups: chemisorbed monolayer, surface halide, bulk-like halide. Formation of monolayer structures is described in terms of surface phase transitions. Surface halide phases are considered to be intermediates between chemisorbed halogen and bulk halide. The modern theoretical approaches in studying the dynamics of metal halogenation reactions are also presented. (C) 2018 Elsevier B.V. All rights reserved.
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