期刊
ARKIVOC
卷 -, 期 -, 页码 226-242出版社
ARKAT USA INC
DOI: 10.3998/ark.5550190.0013.317
关键词
Imidazolium salt; N-heterocyclic carbene; palladium complex; single-crystal X-ray diffraction structure; steric shielding
资金
- University of Heidelberg
- Graduate Academy
The N-heterocyclic carbene (NHC) ligand IPr** features substituents of unprecedented steric demand (IPr** = 1,3-bis[2,6-bis[(4-tert-butylphenyl)methyl]-4-methylphenyl]imidazol-2-ylidene). The NHC structure is an advanced derivative of the IPr system, and of the IPr* by Berthon-Gelloz and Marko. In the IPr** ancillary ligand, two para-methyl are introduced and eight methyl groups of IPr are formally replaced by a 4-tert-butylphenyl substituent, respectively, thereby sterically shielding both a coordinated metal and its second ligand. Favorable features of ligand and late transition metal complexes include high solubility, aesthetic NMR spectra, and a tendency towards crystallization.
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