4.7 Article

Hydrophilicity modification of aramid fiber using a linear shape plasma excited by nanosecond pulse

期刊

SURFACE & COATINGS TECHNOLOGY
卷 344, 期 -, 页码 614-620

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2018.03.057

关键词

Aramid fiber; Nanosecond pulsed discharge; Oxygen atom; Surface modification; Water contact angle

资金

  1. National Key R&D Program of China [2016YFC0207200]
  2. National Natural Science Foundation of China [51377014, 51407022, 51677019]

向作者/读者索取更多资源

In this paper, a linear shape nanosecond pulsed dielectric barrier discharge is generated at atmospheric pressure for improving the hydrophilic property of aramid fibers. The discharge images, waveforms of voltage and current, and optical emission spectra of discharge are obtained to investigate plasma characteristics, and the water contact angles, scanning electron microscopy, and X-ray photoelectron spectroscopy are employed to estimate the modifying effects of plasma and investigate modification mechanisms. It is found that 75 s is an optimal treatment time in air under 2 mm discharge gap, 28 kV pulse peak voltage, and 100 Hz pulse repetition rate, and the energy density of discharge is about 2.1 J/cm(2). The improvement of aramid fiber hydrophilicity is due to the increasing of surface roughness and the formation of polar functional groups such as C-N and O=C-O. Besides, the content of O-2 has an obvious influence on plasma treatment, and C-C is more easily oxidized under a high O-2 concentration owing to the role of O atoms.

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