期刊
ACS APPLIED MATERIALS & INTERFACES
卷 7, 期 15, 页码 8023-8032出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b00294
关键词
full-degradable poly(lactic acid) film; poly(butylene succinate) nanolaminae; gas permeability; mechnical properties
资金
- China Scholarship Council (CSC)
- National Natural Science Foundation of China [51120135002, 21276168, 51473101, 51421061]
- Innovation Team Program of Science & Technology Department of Sichuan Province [2014TD0002]
- Doctoral Program of the Ministry of Education of China [20130181130012]
The traditional approach toward barrier property enhancement of poly(lactic acid) (PLA) is the incorporation of sheet-like fillers such as nanoclay and graphene, unfortunately leading. to the sacrificed biocompatibility and degradability. Here we unveil the first application of a confined flaking technique to establish the degradable nanolaminar poly(butylene succinate) (PBS) in PIA films based on PLA/PBS in situ nanofibrillar composites. The combination of high pressure (10 MPa) and appropriate temperature (160 degrees C) during the flaking process desirably enabled sufficient deformation of PBS nanofibrils and retention of ordered PLA channels. Particularly, interlinked and individual nanosheets were created in composite films containing 10 and 20 wt % PBS, respectively, both of which presented desirable alignment and large width/thickness ratio (nanoscale thickness with a width of 428 +/- 13.1 and 76.9 +/- 8.2 mu m, respectively). With the creation of compact polymer nano-barrier walls, a dramatic decrease of 86% and 67% in the oxygen permeability coefficient was observed for the film incorporated with well-organized 20 wt % PBS nanosheets compared to pure PLA and pure PBS (1.4 and 0.6 x 10(-14) cm(3).cm.cm(-2).s(-1).Pa-1), respectively. Unexpectedly, prominent increases of 21% and 28% were achieved in the tensile strength and modulus of composite films loaded 20 wt % PBS nanosheets compared to pure PLA films, although PBS intrinsically presents poor strength and stiffness. The unusual combination of barrier and mechanical performances established in the fully degradable system represent specific properties required in packaging beverages, food and medicine.
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