期刊
SOLID STATE IONICS
卷 320, 期 -, 页码 387-391出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ssi.2018.03.028
关键词
Fe-substituted lithium sulfide; Low crystalline material; Lithium sulfur battery; Pair distribution function analysis; High capacity
资金
- METI
- NEDO
The structure of Fe-substituted Li2S-based positive electrode material Li8FeS5 was analyzed using high-energy Xray total scattering measurements. Pair distribution function (PDF) analyses indicated that the mechanically milled Li8FeS5 sample could best be described as having an anti-fluorite structure in which Fe ions partially occupy Li sites in the Fm (3) over barm unit cell. The electrochemical properties of a cell utilizing Li8FeS5 as the positive electrode were also consistent with this structural model.
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