期刊
SOLID STATE IONICS
卷 318, 期 -, 页码 95-101出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ssi.2017.07.021
关键词
Solid polymer electrolytes; Nanocomposite material; Lithium bis(fluorosulfonyl)imide; Lithium bis(trifluoromethanesulfonyl)imide; Lithium metal batteries
资金
- GV-ELKARTEK from the Basque Government
- MINECO RETOS from Spanish Government [ENE2015-64907-C2-1-R]
Nanocomposite solid polymer electrolytes (NSPEs) comprising lithium salt based on two representative sulfonylimide anions (i.e., bis(fluorosulfonyl)imide ([N(SO2F)(2)](-), FSI-) and bis(trifluoromethanesulfonyl)imide ([N(SO2CF3)(2)](-), TFSI-)) have been prepared by simply dissolving the corresponding lithium salt in poly(ethylene oxide) matrix in the presence of inert nano-sized Al2O3 fillers. The physicochemical and electrochemical properties of the FSI- and TFSI-based NSPEs are investigated, in terms of phase transition, ion transport behavior, chemical and electrochemical compatibility with Li metal. With the addition of nano-sized Al2O3 fillers, a significant improvement in chemical and electrochemical compatibility with Li metal has been observed in both the FSI- and TFSI-based NSPEs. Particularly, the symmetric cell using the FSI-based NSPE can be continuously cycled for > 1000 h at 70 degrees C. The Li vertical bar LiFePO4 cell with the FSI-based NSPEs shows good cycling stability and capacity retention. These promising results make them attractive electrolytes for safe and stable rechargeable Li metal batteries.
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