期刊
SMALL
卷 14, 期 15, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201703989
关键词
cascade systems; heterogeneous electron transfer rate constant; in situ; multiple electron transfer; photocatalysis
类别
资金
- National Natural Science Foundation of China [21327005, 21575115, 21705117]
- Program for Chang Jiang Scholars and Innovative Research Team, Ministry of Education, China [IRT-16R61]
- Program of Innovation and Entrepreneurial for Talent, Lan Zhou, Gansu Province, China [2014-RC-39]
Recombination of photogenerated electron-hole pairs is extremely limited in the practical application of photocatalysis toward solving the energy crisis and environmental pollution. A rational design of the cascade system (i.e., rGO/Bi2WO6/Au, and ternary composites) with highly efficient charge carrier separation is successfully constructed. As expected, the integrated system (rGO/Bi2WO6/Au) shows enhanced photocatalytic activity compared to bare Bi2WO6 and other binary composites, and it is proved in multiple electron transfer (MET) behavior, namely a cooperative electron transfer (ET) cascade effect. Simultaneously, UV-vis/scanning electrochemical microscopy is used to directly identify MET kinetic information through an in situ probe scanning technique, where the fast and slow heterogeneous ET rate constants (K-eff) of corresponding photocatalysts on the different interfaces are found, which further reveals that the MET behavior is the prime source for enhanced photocatalytic activity. This work not only offers a new insight to study catalytic performance during photocatalysis and electrocatalysis systems, but also opens up a new avenue to design highly efficient catalysts in photocatalytic CO2 conversion to useful chemicals and photovoltaic devices.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据