期刊
CHINESE JOURNAL OF CATALYSIS
卷 33, 期 11, 页码 1778-1782出版社
SCIENCE PRESS
DOI: 10.1016/S1872-2067(11)60471-3
关键词
gold; copper; mesoporous titania; stability; carbon monoxide; oxidation
资金
- National High Technology Research and Development Program of China (863 Program) [2006AA03Z455]
- National Basic Research Program of China (973 Program) [2009CB226103]
- National Natural Science Foundation Committee [20731160614]
- Hong Kong Research Grants Council Joint Scientific Research Foundation [20731160614]
- National Natural Science Foundation of China [21136001, 21136004, 20976080]
- Innovation Foundation for Graduate Students of Jiangsu Province [CXLX12_0447]
An Au-Cu bimetal catalyst was prepared by deposition-precipitation (urea) of gold and copper species on mesoporous TiO2 and activation with H-2. The sample was characterized by N-2 adsorption/desorption, X-ray diffraction, ultraviolet-visible spectroscopy, and high-resolution transmission electron microscopy. The results showed that the Au and Cu species formed an Au-Cu alloy and were well dispersed on the mesoporous TiO2. According to CO oxidation test results, it was found that the catalytic activity of gold was enhanced by copper. The Au-Cu bimetal catalyst supported on mesoporous TiO2 showed better catalytic stability in CO oxidation than the Au catalyst supported on mesoporous TiO2 and the nonporous TiO2-supported catalysts. This may be related to the effects of both Au-Cu alloying and the mesostructure of TiO2.
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