Hydrogen trapping in carbon supersaturated α iron and its decohesion effect in martensitic steel

Our first-principles calculations demonstrate that hydrogen is more stable in carbon supersaturated martensite than in a iron, due to the carbon-induced tetragonality in martensite lattice. The trapped hydrogen leads to remarkable decohesion between (110) planes both inside the martensite and along the martensite/ferrite interface, with the former being more significant than the latter. This decohesion can explain recent precise observations that in martensite/ferrite dual-phase steels the hydrogen-promoted crack was initiated in the martensite region and that in lath martensite steel it propagated not on lath boundaries but showed quasi-cleavage feature along (110) planes at very high hydrogen concentration. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.