期刊
RUSSIAN CHEMICAL BULLETIN
卷 67, 期 2, 页码 260-264出版社
PLEIADES PUBLISHING INC
DOI: 10.1007/s11172-018-2068-9
关键词
asymmetric hydrogenation; phosphoramidites; mixed ligands; 1,5-benzo-diazepin-2-ones
资金
- Russian Foundation for Basic Research [17-03-00483]
A series of phosphoramidite ligands was tested in the asymmetric hydrogenation of 4-arylsubstituted 1,3-dihydro-2H-benzodiazepine-2-ones and up to 52% ee was achieved. The effects of various factors (solvents, hydrogen pressure, and addition of phosphine ligands) on the hydrogenation were studied.
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