期刊
REACTION KINETICS MECHANISMS AND CATALYSIS
卷 124, 期 2, 页码 651-667出版社
SPRINGER
DOI: 10.1007/s11144-018-1374-4
关键词
Metal organic frameworks; CO preferential oxidation; Copper oxide; Ceria; Template
资金
- National Natural Science Foundation of China [21406053]
- Natural Science Foundation of Hebei province of China [B2014208141]
A facile one-pot strategy of using CeBTC MOF as template and precursor was explored to prepare rod-like inverse CeO2-CuO catalysts. The inverse CeO2-CuO catalysts were characterized by using techniques of N-2 adsorption and desorption, XRD, TEM, TPR and XPS. The results indicated that the rod-like inverse CeO2-CuO catalysts maintained the shapes of CeBTC MOF templates. The Cu0.71Ce0.29 catalysts exhibited excellent catalytic performance which was attributed to the strong synergistic effect between CuO and CeO2 and subsequent formation of reduced copper species.
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