Efficient decontamination of naturally occurring radionuclide from aqueous carbonate solutions by ion flotation process

The present study evaluates the performance of ion flotation process for removal of uranyl tricarbonate complex, UO2 (CO3)(3)(4-), which is the dominant species in many aqueous media particularly seawater, from aqueous solutions using cetyltrimethylammonium bromide, CTAB, as a cationic surfactant. Flotation of UO2 (CO3)(3)(4-) as a function in the solution pH is investigated in absence and in presence of carbonate. Removal percentage >99% is achieved in the pH range 8.5-11.5 in presence of 5 x 10(-3) M carbonate. The influence of concentrations of ethanol (0.1-2% v/v) and CTAB (5 x 10(-5)-1.4 x 10(-3) M) show that UO2 (CO3)(3)(4-) is efficiently removed at concentrations of 0.5-1.5% v/v and 4 x 10(-4)-1 x 10(-3) M, respectively. Based on the obtained kinetic data, the flotation mechanism and the flotation rate are investigated using two different flotation models. Floatability of UO2 (CO3)(3)(4-) in presence of different cations (Ba2+, Ca2+, Mg2+ and Sr2+) and anions (NO3-, Br-, Cl-, SO42- and HPO42-) is studied. Except for Mg2+ and NO3-, the flotation efficiency of UO2 (CO3)(3)(4-) is significantly decreased at concentrations higher than 1 x 10(-3) and 5 x 10(-3) M of the studied cations and anions, respectively. Ion flotation process is efficiently applied for removal of uranium(VI), R%>98.5%, from seawater. Accordingly, ion flotation can be considered as a promising technique and thus its feasibility for removal and/or recovery of uranium(VI) from many aqueous environment.