4.7 Article

Green and sustainable anticorrosive coating derived from waterborne linseed alkyd using organic-inorganic hybrid cross linker

期刊

PROGRESS IN ORGANIC COATINGS
卷 122, 期 -, 页码 189-198

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2018.05.026

关键词

Renewable; Hybrid; MF/IPTES; s-triazine; Anticorrosive

资金

  1. University Grant Commision (UGC), New Delhi, India [F.12006 (BSR/7-192/2007)]

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In near future, bio-based polymer coatings are expected to gradually replace the fossil oil based coating materials. However, extensive application of bio-based polymer is still a challenge because of its several limitations. The use of organic-inorganic hybrid cross linker is one of the interesting strategies used for the processing of highly crosslinked polymer coatings with improved mechanical and anticorrosive performance. Thus present work reports the preparation of organic-inorganic hybrid (OIH) cross linker using melamine formaldehyde (MF) and 3 isocynatopropyl triethoxy silane (IPTES). The structural characterization was carried out using various spectroscopic techniques, which provide ample evidence in favor of MF/IPTES cured alkyd formation. The impact of OIH cross linker on various properties like physico-mechanical, adhesion, thermal stability and anticorrosive properties was investigated systematically. The enhancement in aforementioned properties could be explained in terms of synergistic effect of s-triazine ring of melamine formaldehyde and IPTES.

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