期刊
POLYMER CHEMISTRY
卷 9, 期 17, 页码 2290-2294出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8py00270c
关键词
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资金
- NSF [DMR-1607971]
- Center for Neutron Science at the University of Delaware
- NRF for the National Creative Research Initiative Center for Intelligent Hybrids [70NANB10H256, 2010-0018290]
- University of Delaware's funding provided through the Department of Materials Science and Engineering [W911NF-17-2-0186]
- Kuraray
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1607971] Funding Source: National Science Foundation
In this report, a new class of functional chalcogenide hybrid inorganic/organic polymers (CHIPs) bearing free aryl amine groups that are amenable to post-polymerization modifications were synthesized. These functional CHIPs were synthesized via the inverse vulcanization of elemental sulfur with 4-vinylaniline without the need for functional group protection of amines. This polymer is the first example of a polysulfide or CHIP material to carry a useful primary amine functional group which can be successfully post functionalized with acid chlorides and isocyanates to improve the mechanical properties.
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