期刊
POLYHEDRON
卷 148, 期 -, 页码 81-87出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2018.03.032
关键词
Coordination polymer; Structure; Photocatalysis; Electrochemical performance; 1-Imidazol-1-yl-3-(1,2,4-triazol-4-yl)propane
资金
- National Natural Science Foundation of China [21171126]
- Natural Science Foundation of Jiangsu Province [BK20161212]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- State and Local Joint Engineering Laboratory for Functional Polymeric Materials
- project of Scientific and Technological Infrastructure of SuZhou [SZS201708]
- Russian Science Foundation [16-13-10158]
- National Key R&D Program of China [2017YFB0703200]
- Russian Science Foundation [16-13-10158] Funding Source: Russian Science Foundation
A copper(II) coordination polymer {[Cu(itp)(ip)][Cu-4(OH)(2)(itp)(ip)(3)]center dot 4H(2)O})(n), (1) (itp = 1-imidazol-1-yl-3-(1,2,4-triazol-4-yl)propane, ip = isophthalate) was synthesized and characterized. 1 exhibits an intriguing 2-fold interpenetrating array of (4,6)-coordinated 3D nets of the fsc topological type, which are based on the 4-coordinated single copper(II) and 6-coordinated tetranuclear hydroxy copper(II) [Cu-4(mu(3)-OH)(2)] cluster. 1 is a highly efficient and universal photocatalyst for the degradation of the organic dyes methylene blue (MB), rhodamine B (RhB) and methyl orange (MO) under visible light irradiation. Electrochemical performance of 1 was also measured. (C) 2018 Elsevier Ltd. All rights reserved.
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