期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 20, 期 35, 页码 22445-22454出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cp00859k
关键词
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资金
- National Natural Science Foundation of China [51527901, 51475447, 51575253, 21663024]
- China Postdoctoral Science Foundation [2016M602809]
The friction behaviors of highly sp(3)-hybridized carbon films, including ultra-nanocrystaine diamond and diamond-like carbon materials, strongly depend on the atmosphere. However, the roles of the corresponding molecules in the interfacial bonding characteristics remain a subject of debate. By means of density functional theory calculations, this study aims to fill a knowledge gap about the correlation between the evolving contact quality induced by the adsorption of molecules, and the friction behavior of highly sp(3)-bonded carbons. The results prove that gas-solid adsorption is responsible for the diversity in friction coefficients of ultra-nanocrystaine diamond and diamond-like carbons in different atmospheres. This study emphasizes the role of terminal states in friction coefficients, and demonstrates that electron lubrication is another available strategy for hydrogenated diamond-like carbons to achieve ultra-low friction. This conclusion is validated by the ultra-low friction coefficient (similar to 0.009) of hydrogenated diamond-like carbons in a dry nitrogen atmosphere. These findings provide atomic scale descriptions of the surface passivation mechanisms for ultra-nanocrystaine diamond and diamond-like carbons, which contribute to our understanding of their macro-scale friction behaviors.
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