4.6 Article

The effect of regioisomerism on the photophysical properties of alkylated-naphthalene liquids

期刊

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 20, 期 5, 页码 2970-2975

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cp05584f

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资金

  1. JSPS KAKENHI [JP25104011, JP15H03801, JP16H00850, JP16H00782]
  2. NIMS Molecule & Material Synthesis Platform in the Nanotechnology Platform Project''
  3. MEXT-Supported Program for the Strategic Research Foundation at Private Universities, from MEXT, Japan
  4. TIA collaborative research promotion program KAKEHASHI''
  5. Grants-in-Aid for Scientific Research [25104011, 15K21740, 16H00782, 15H03801, 16H00850] Funding Source: KAKEN

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Novel regioisomeric alkylated-naphthalene liquids were designed and synthesized. In the solvent-free liquid state, 1-alkyloxy regioisomers showed excimeric luminescence, whereas 2-alkyloxy analogues exhibited monomer-rich luminescence features. Correlations among the molecular structures and the photophysical, calorimetric, and rheological properties are presented, demonstrating the impact of regioisomerism on the alkylated-chromophore liquid systems.

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