期刊
ORGANOMETALLICS
卷 37, 期 4, 页码 505-516出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.7b00753
关键词
-
资金
- National Science Foundation [CHE-1402149, CHE-1664580]
- Cornell University
A tutorial addressing the activation of carbon hydrogen bonds via the 1,2-RH-addition to high oxidation state, early metal XnM=NR complexes is described. Details regarding the reverse 1,2-RH-elimination from X-n(R')M-NHR, are also presented. The overall process is discussed as follows: (1) electrophilicity and electronics; (2) general mechanism; (3) kinetics of 1,2-RH-elimination; (4) periodic trends; (5) alkane complexes; (6) kinetic isotope effects (KIEs); (7) RH activation selectivities; and (8) future directions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据