期刊
ORGANIC LETTERS
卷 20, 期 14, 页码 4375-4378出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01863
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资金
- JSPS KAKENHI [JP18K05106]
Herein, a novel approach for the trideuteriomethylation of aryl halides using nickel and nucleophilic cobalt catalysts and the readily available trideuteriomethyl p-toluenesulfonate (CD3OTs) is described. This method provides access to a wide range of CD3-containing arenes. Moreover, a transmethylation step is revealed as crucial in the nickel/cobalt catalytic mechanism.
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