期刊
ORGANIC LETTERS
卷 20, 期 14, 页码 4362-4366出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01841
关键词
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资金
- NSFC [21472071, 21602087]
- PAPD of Jiangsu Higher Education Institutions
- Outstanding Youth Fund of JSNU [YQ2015003]
- NSF of Jiangsu Province [BK20160212]
- Qing Lan Project of Jiangsu Education Committee
An unusual catalytic double [2 + 2] cycloaddition relay reaction of yne-allenones with unactivated alkenes and alkynes has been achieved, which enabled C-C triple-bond cleavage to access more than 60 examples of functionalized phenanthren-9-ols with generally good yields. This reaction provides a regioselective and practical method for the construction of carbocyclic ring systems with a high degree of functional group compatibility. Aside from surveying the scope of this transformation, mechanistic details of this process are provided by conducting systematic theoretical calculations.
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