期刊
ORGANIC LETTERS
卷 20, 期 2, 页码 409-412出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03707
关键词
-
资金
- National Program for Thousand Young Talents of China
- 111 Project
A chemodivergent copper-catalyzed ring opening of cyclokettoe oximes via radical-mediated C-C bond cleavage under redox-neutral conditions is described. This method allows the divergent synthesis of gamma- and delta-acyloxylatect alkoxylated, and hydroxylated nitrites while avoiding the use of toxic cyanide reagents. Moreover, these reactions proceed under very mild conditions with good functional group tolerance. Notably, ring-opening reactions of the less-strained substrate cyclopentanone oxinie also proceeded well under the established conditions.
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