期刊
ORGANIC LETTERS
卷 20, 期 11, 页码 3273-3277出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01145
关键词
-
资金
- National Key Research and Development Program [2016YFA0202900]
- National Natural Science Foundation of China [21572256]
- Science and Technology Commission of Shanghai Municipality [18XD1405000]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Shanghai Institute of Organic Chemistry [sioczz201807]
A gold-catalyzed cycloisomerization of ynamide-ynes via a formal dehydro-Diels-Alder reaction has been developed, providing an attractive route to diversely substituted benzo[b]carbazoles. The reaction likely proceeds via regioselective attack of the pendant alkyne moiety to a keteniminium ion intermediate followed by benzannulation. The method offers several advantages such as high efficiency, mild reaction conditions, and wide functional group tolerance and serves as a highly useful complement to the thermal DDA reactions of ynamide-ynes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据