期刊
ORGANIC LETTERS
卷 20, 期 6, 页码 1680-1683出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00520
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资金
- NSFC [21402129, 21372165, 21572142]
- State Key Laboratory of Fine Chemicals, Comprehensive Training Platform of Specialized Laboratory, College of Chemistry, and Analytical & Testing Center, Sichuan University [KF 1508]
Visible-light-driven enantiodifferentiating photodimerization of 2-anthracenecarboxylic acid (AC) sensitized by Schiff base Pt(II) complex-grafted y-cyclodextrins leads the first triplet triplet annihilation-based catalytic photochirogenesis. The syn-head-to-tail (HT) photodimer 2 was achieved in up to 31.4% ee at 61.0% conversion in the presence of 0.5% equiv of the photocatalyst.
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